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- W2039719049 abstract "Abstract The electron spin resonance of gamma and ultraviolet irradiated tetrabutylammonium halides [CH3(CH2)3]4NX (X=I,Cl,Br), tetrabutylammonium hydrogen sulfate [CH3(CH2)3]4NHSO4, tetrabutylammonium periodate [CH3(CH2)3]4NIO4, and ultraviolet photolyzed tetramethylammonium iodide, (CH3)4NI, and tetramethylphosphonium iodide, (CH3)4PI have been investigated between 140 and 350 K. The gamma and ultraviolet irradiation damage centers in tetrabutylammonium compounds were attributed to CH3—CH…—CH…—CH2, radicals, and ultraviolet photolysis damage centers in tetramethylammonium and phosphonium iodides were attributed to ĊH3 radicals. The g values of both radicals are found to be isotropic and g = 2.0030 and 2.0037 respectively to the methylallyl and the methyl radicals. The hyperfine coupling constants of the free electron to the protons in the radicals are reported and discussed. Key Words: ESRultravioletphotolysistetrasubstituted" @default.
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- W2039719049 date "1992-05-01" @default.
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- W2039719049 title "ESR of Gamma Irradiation and Ultraviolet Photolysis Products in Some Tetrasubstituted Ammonium Compounds" @default.
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- W2039719049 doi "https://doi.org/10.1080/00387019208018190" @default.
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