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• W2039735460 abstract "Abstract One novel 3D cadmium coordination polymer, namely, {[Cd2(bptc4 −)(ox2 −)0.5(H2O)2] · 4.5H2O}n (1), has been hydrothermally synthesized through a reaction of 2,3′,4,5′-biphenyltetracarboxylic acid (H4bptc) with divalent cadmium salt in the presence of a second ligand (ox = oxalic acid). X-ray single crystal structure analysis reveals that tetranuclear cadmium clusters are formed by linking two Cd1 and two Cd2 ions with carboxyl groups. Each ox2 − ligand, with a bidentate chelating mode, connects two Cd2 ions from two adjacent tetranuclear clusters to afford 1D zigzag cadmium cluster chains. Furthermore, 1D chains are connected by bptc4 − ligands to extend a 3D framework with one-dimensional channels along the [001] direction. From a topology view, complex 1 exhibits an unprecedented 2-nodal 4, 10-connected net with the Schlafli symbol of {46}2{49. 512.622.72}. The luminescence analyses reveal that complex 1 shows an emission maximum at 437 nm, which may be attributed to the intra-ligand transition. A red shift of 31 nm compared with H4bptc ligand was observed and the luminescent decay lifetime is 2.74 ns, which indicates that it might be a potential blue light-emitting candidate. In addition, it was also characterized by elemental, IR spectra, PXRD and TG analyses." @default.
• W2039735460 created "2016-06-24" @default.
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• W2039735460 date "2015-05-01" @default.
• W2039735460 modified "2023-09-23" @default.
• W2039735460 title "One novel 3D tetranuclear cadmium coordination polymer based on 2,3′,4,5′-biphenyltetracarboxylic acid: Synthesis, crystal structure and luminescence" @default.
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• W2039735460 doi "https://doi.org/10.1016/j.inoche.2015.03.019" @default.
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