Matches in SemOpenAlex for { <https://semopenalex.org/work/W2039771941> ?p ?o ?g. }
Showing items 1 to 77 of
77
with 100 items per page.
- W2039771941 endingPage "261" @default.
- W2039771941 startingPage "256" @default.
- W2039771941 abstract "The diastereoselective Michael alkylation of alpha-substituted and alpha,alpha'-disubstituted cyclohexanone benzylimines with ethylidenemalonate diesters was carried out for mechanistic and synthetic purposes. In the first case, an inverse regioselectivity occurred in comparison with what is generally observed since the Michael adducts resulted from alkylation of the non substituted enamine tautomer. With alpha,alpha'-disubstituted imines, in all cases, the stereochemistry of the major diastereomer was the one anticipated from a mechanism including a chairlike complex approach with a preferred exo position for the beta-methyl group of the ethylidenemalonic acid diesters. Furthermore, diphenyl 2-ethylidenemalonate 4 was found to be a highly electrophilic synthetic equivalent of crotonic esters." @default.
- W2039771941 created "2016-06-24" @default.
- W2039771941 creator A5003383965 @default.
- W2039771941 creator A5008602795 @default.
- W2039771941 creator A5012012323 @default.
- W2039771941 creator A5071943509 @default.
- W2039771941 date "2000-12-09" @default.
- W2039771941 modified "2023-10-16" @default.
- W2039771941 title "Reaction of Cyclohexanone Benzylimines with Ethylidenemalonate Diesters. Diphenyl 2-Ethylidenemalonate: A Highly Electrophilic Synthetic Equivalent of Crotonic Esters" @default.
- W2039771941 cites W1978517889 @default.
- W2039771941 cites W1988521352 @default.
- W2039771941 cites W2051847782 @default.
- W2039771941 cites W2316114041 @default.
- W2039771941 cites W2949143774 @default.
- W2039771941 cites W3004511368 @default.
- W2039771941 cites W4241845182 @default.
- W2039771941 doi "https://doi.org/10.1021/jo005657h" @default.
- W2039771941 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/11429908" @default.
- W2039771941 hasPublicationYear "2000" @default.
- W2039771941 type Work @default.
- W2039771941 sameAs 2039771941 @default.
- W2039771941 citedByCount "24" @default.
- W2039771941 countsByYear W20397719412013 @default.
- W2039771941 countsByYear W20397719412014 @default.
- W2039771941 countsByYear W20397719412015 @default.
- W2039771941 countsByYear W20397719412018 @default.
- W2039771941 crossrefType "journal-article" @default.
- W2039771941 hasAuthorship W2039771941A5003383965 @default.
- W2039771941 hasAuthorship W2039771941A5008602795 @default.
- W2039771941 hasAuthorship W2039771941A5012012323 @default.
- W2039771941 hasAuthorship W2039771941A5071943509 @default.
- W2039771941 hasConcept C111233374 @default.
- W2039771941 hasConcept C138716334 @default.
- W2039771941 hasConcept C155647269 @default.
- W2039771941 hasConcept C161790260 @default.
- W2039771941 hasConcept C164361826 @default.
- W2039771941 hasConcept C178790620 @default.
- W2039771941 hasConcept C185592680 @default.
- W2039771941 hasConcept C2776378156 @default.
- W2039771941 hasConcept C2780450521 @default.
- W2039771941 hasConcept C50027330 @default.
- W2039771941 hasConcept C59759590 @default.
- W2039771941 hasConcept C71240020 @default.
- W2039771941 hasConceptScore W2039771941C111233374 @default.
- W2039771941 hasConceptScore W2039771941C138716334 @default.
- W2039771941 hasConceptScore W2039771941C155647269 @default.
- W2039771941 hasConceptScore W2039771941C161790260 @default.
- W2039771941 hasConceptScore W2039771941C164361826 @default.
- W2039771941 hasConceptScore W2039771941C178790620 @default.
- W2039771941 hasConceptScore W2039771941C185592680 @default.
- W2039771941 hasConceptScore W2039771941C2776378156 @default.
- W2039771941 hasConceptScore W2039771941C2780450521 @default.
- W2039771941 hasConceptScore W2039771941C50027330 @default.
- W2039771941 hasConceptScore W2039771941C59759590 @default.
- W2039771941 hasConceptScore W2039771941C71240020 @default.
- W2039771941 hasIssue "1" @default.
- W2039771941 hasLocation W20397719411 @default.
- W2039771941 hasLocation W20397719412 @default.
- W2039771941 hasOpenAccess W2039771941 @default.
- W2039771941 hasPrimaryLocation W20397719411 @default.
- W2039771941 hasRelatedWork W1988928236 @default.
- W2039771941 hasRelatedWork W2000027971 @default.
- W2039771941 hasRelatedWork W2049273629 @default.
- W2039771941 hasRelatedWork W2071192748 @default.
- W2039771941 hasRelatedWork W2081247919 @default.
- W2039771941 hasRelatedWork W2105466274 @default.
- W2039771941 hasRelatedWork W2375547858 @default.
- W2039771941 hasRelatedWork W2914268038 @default.
- W2039771941 hasRelatedWork W3002554271 @default.
- W2039771941 hasRelatedWork W4283711622 @default.
- W2039771941 hasVolume "66" @default.
- W2039771941 isParatext "false" @default.
- W2039771941 isRetracted "false" @default.
- W2039771941 magId "2039771941" @default.
- W2039771941 workType "article" @default.