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• W2039772054 abstract "Topochemically polymerized sodium 10,12-pentacosadiynoate (PCDA-Na) microcrystals show an irreversible red-to-blue chromatic transition accompanied by a distinct structural evolution upon initial thermal treatment, and show a subsequent completely reversible blue-to-red chromatic transition upon further thermal stimuli. Visible absorption spectroscopy, X-ray diffraction (XRD), and differential scanning calorimetry (DSC) are used to investigate the thermochromatic transition behavior of the polydiacetylenic microcrystals. Brief quantum mechanical geometry optimization is employed to explain the lattice dimensional change during the irreversible red-to-blue chromatic transition of the metastable polydiacetylenic crystals." @default.
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• W2039772054 date "2006-03-22" @default.
• W2039772054 modified "2023-10-17" @default.
• W2039772054 title "Thermochromatism and Structural Evolution of Metastable Polydiacetylenic Crystals" @default.
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• W2039772054 doi "https://doi.org/10.1021/jp060309q" @default.
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