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- W2039772686 abstract "Abstract The reaction between an aqueous solution of Mn(NO3)2and MnO or ZnO gives a white-beige powder of (MnxZn1-x) (OH)(NO3(H2O) with x = 1.0 or x = 0.53, respectively. These new manganese(II)-based hydroxynitrates are isostructural with Zn(OH)(NO3)(H2O) and crystallize in the monoclinic system, space group P21/c, with a = 18.070(2) A, b = 3.3226(5) A, c = 14.362(2) A, and β = 114.960(6)° for (Mn0.53Zn0.47)(OH)(NO3)(H2O) and a = 18.154(2) A, b = 3.3721(4) A, c = 14.456(1) A, and β = 114.934(6)° for Mn(OH)(NO3)(H2O). The manganese(II) atoms are octahedrally coordinated within zigzag double chains running along the b direction. Magnetic measurements from room temperature down to 4.2 K show a quasi-one-dimensional behavior of this special array of classical S = 5/2 spins." @default.
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- W2039772686 date "1995-08-01" @default.
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- W2039772686 title "Synthesis and Characterization of New Quasi-One-Dimensional Mn(II) Hydroxynitrates (MnxZn1-x)(OH)(NO3)H2O (x = 0.53, 1.00)" @default.
- W2039772686 doi "https://doi.org/10.1006/jssc.1995.1306" @default.
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