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• W2039773075 abstract "Abstract Optically pure thallium (1R)-(−)-9,9-dimethyltricyclo[6.1.1.02′6]deca-2,5-dienide (TIPCp) reacts with [(n6-arene)RuCl2]2 (arene = C6H6, MeC6H4, p-MeC6H4CHMe2, Me6C6) and NH4PF6 to form two isomers of the complexes [(n5-PCp)Ru(n6-arene)]PF6. The π-facial stereoselectivity for coordination of PCp is a function of the steric bulk of the arene increasing from a 1:1 (C6H6) to a 14:1 (Me6C6) exolendo isomer ratio. New complexes were characterized by elemental analyses, physical properties, differential pulse voltammetry and 1H and 13C{1H} one- and two-dimensional NMR spectroscopy. The structure of [(n5-PCp)Ru(n6-Me6C6)]PF6 was confirmed by X-ray crystallography. This compound crystallized in the acentric space group C2221 in a unit cell with the following dimensions: a = 11.451(4), b = 13.426(5), c = 31.249(3) A, V= 4804(3) A3, Z = 8. Refinement converged to R(F) = 0.056 for 1723 independent observed (I>3σ(I)) reflections. Ruthenium coordinates to the less sterically hindered exo face of the PCp ligand, anti to the gem-dimethyl group, and is closer to the arene (Ru-ring centroid = 1.73 A) than to the PCp ligand (Ru-ring centroid = 1.79 A)." @default.
• W2039773075 created "2016-06-24" @default.
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• W2039773075 date "1994-06-01" @default.
• W2039773075 modified "2023-09-24" @default.
• W2039773075 title "π-Facial selectivities in the coordination of an optically pure fused cyclopentadienyl ligand to arene ruthenium moieties. NMR spectral and structural characterization of a single diastereomer of [(PCp)Ru(Me6C6)]PF6" @default.
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• W2039773075 doi "https://doi.org/10.1016/0020-1693(94)03840-6" @default.
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