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- W2039776765 abstract "A novel A-σ-π-σ-A type of silicon-bridged compound, 1,4-bis(cyanophenyldimethylsilyl)benzene (CPDMB), was synthesized and fully characterized by FT-IR, 1 H NMR, 13 C NMR, HRMS, and single crystal X-ray diffraction. Ultraviolet properties and steady-state fluorescence of CPDMB were studied. The concentration self-quenching phenomena of CPDMB were found in 2-propanol, THF, and CH 2 Cl 2 . It can be well interpreted by photoinduced self-assembly behavior (J-aggregate) of the CPDMB in solvents. Moreover, the effects of solvents on the fluorescence self-quenching phenomena were also investigated. In order to interpret the novel photoelectric properties of CPDMB, DFT calculations on gas phase CPDMB were carried out." @default.
- W2039776765 created "2016-06-24" @default.
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- W2039776765 date "2010-08-01" @default.
- W2039776765 modified "2023-09-28" @default.
- W2039776765 title "Fluorescence self-quenching and charge transfer of a novel A-σ-π-σ-A type of silicon-bridged compound" @default.
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- W2039776765 doi "https://doi.org/10.1016/j.jphotochem.2010.07.002" @default.
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