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• W2039860173 abstract "Two cobalt(II) coordination polymers, {[Co(μ-4,4′-bipy)(4,4′-bipy)2(H2O)2]·(OH)3·(Me4N)·4,4′-bipy·4H2O}n (1) and {[Co(μ-4,4′-bipy)(H2O)4]·suc·4H2O}n (2) (4,4′-bipy = 4,4′-bipyridine, suc = succinate dianions), were hydrothermally synthesized and structurally characterized by X-ray diffraction analysis, UV-Vis-NIR, and ICP. The main structure feature common to the both polymers is presence of the infinite linear chains, [Co(μ-4,4′-bipy)(4,4′-bipy)2(H2O)2]n (1) and [Co(μ-4,4′-bipy)(H2O)4]n (2), respectively. In 1, the chains are further linked by the hydrogen-bond and π-π stacking interaction, producing extended layer structure. The 4,4′-bipy molecules in 1 play three different roles. In 2, the chains are linked into three-dimensional network structure via complicated hydrogen bonding system. The variable temperature (2.0∼300 K) magnetic susceptibility of 1 indicates a tendency of spin-transition in the temperature range of 110 K to 22 K, which attributes to the transition of high-spin to low-spin from Co2+(d7) ion. Also, the result of surface photovoltage spectroscopy (SPS) reveals that the polymer 1 has significant photoelectric conversion property in the region of 300-800 nm." @default.
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• W2039860173 date "2006-10-01" @default.
• W2039860173 modified "2023-09-27" @default.
• W2039860173 title "Hydrothermal Synthesis, Structural Characterization, Magnetic and Photoelectric Properties of Two Cobalt(II) Coordination Polymers" @default.
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• W2039860173 doi "https://doi.org/10.1002/zaac.200600197" @default.
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