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- W2039883933 abstract "Abstract Ytterbium tri-fluoromethanesulfonate (YbTFMS) single crystals are prepared from the slow evaporation of the aqueous solution of YbTFMS and the principal magnetic susceptibility perpendicular to the c -axis of the hexagonal crystal ( χ ⊥ ) is measured from 300 K down to 13 K. Principal magnetic anisotropy Δ χ (= χ ∥ − χ ⊥ ) is measured from 300 K down to 80 K which provides principal magnetic susceptibility parallel to the c -axis ( χ ∥ ) down to 80 K. Very good theoretical simulation of the observed magnetic properties of YbTFMS has been obtained using one electron crystal field (CF) analysis having C 3h site symmetry. No signature of ordering effect in the observed magnetic data is noticed down to the lowest temperature (13 K) attained, indicating the inter-ionic interaction to be of predominantly dipolar type. The calculated g -values are found to be g ∥ =2.67 and g ⊥ =2.51, respectively. CF analysis provides the electronic specific heat which gives two Schottky anomalies in its thermal variation down to ∼13 K. The temperature dependences of quadrupole splitting and hyperfine heat capacity are studied from the necessary information obtained from the CF analysis." @default.
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- W2039883933 date "2009-01-01" @default.
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- W2039883933 title "Crystal field investigation on the magnetic properties of Yb3+ in Yb(CF3SO3)3·9H2O" @default.
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- W2039883933 doi "https://doi.org/10.1016/j.jpcs.2008.09.002" @default.
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