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- W2039915300 abstract "Orange-red copper(II) complexes of (RS)-3-aminohexahydroazepine (=RS-ahaz), Cu(RS-ahaz)2X2·nH2O (X−=ClO4−, BF4−, NO3−, Br−, I−) were prepared, and the molecular structures of complex 1 (X−=ClO4−; n=0) and complex 2 (X−=Br−; n=2) were determined by the single-crystal X-ray diffraction method. The complex 1 has centrosymmetry, and the complex cation in 1 involves a pair of R- and S-ahaz (R- and S-ahaz refer to (R)-and (S)-3-aminohexahydroazepine) and takes a strict four-coordination geometry, so that 1 is formulated as [Cu(R-ahaz)(S-ahaz)](ClO4)2. The complex cation in 2 resembles closely that of 1, and 2 can be represented as [Cu(R-ahaz)(S-ahaz)]Br2·2H2O. The other orange-red complexes of RS-ahaz (X−=BF4−, NO3−, I−) were concluded to take similar strict four-coordinated structures. Blue-violet hetero-anion complexes Cu(RS-ahaz)2X(ClO4) were obtained from complex 1 and LiX (X−=Cl−, Br−). The crystal structure determination of Cu(RS-ahaz)2Br(ClO4) (=complex 3) revealed that 3 involves a pair of enantiomeric ..." @default.
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- W2039915300 date "1987-07-01" @default.
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- W2039915300 title "Stereochemical Properties of Copper(II) Complexes of (<i>RS</i>)-3-Aminohexahydroazepine: Crystal and Molecular Structures of [(<i>R</i>)-3-Aminohexahydroazepine][(<i>S</i>)-3-aminohexahydroazepine]copper(II) Diperchlorate, [Cu(<i>R</i>-ahaz)(<i>S</i>-ahaz)](ClO<sub>4</sub>)<sub>2</sub>and Related Complexes" @default.
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- W2039915300 doi "https://doi.org/10.1246/bcsj.60.2581" @default.
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