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• W2039927377 abstract "The CD associated with the lowest energy π → π* transition is discussed for compounds in which the chromophore of interest is a single or conjugated olefinic double bond, with an allylic oxygen substituent. It is shown that the Cotton effect concerned is usually intense, with positive sign if the chirality of the system CCCO is right-handed and negative if the chirality is left-handed. In cases where the olefinic double bond is conjugated and the conjugated system is itself skewed, the chiralities of the two systems may be opposed. When this occurs, the sign of the Cotton effect is found usually to accord with the helical sense of the system CCCO. The basic phenomenon is believed to be the same as that underlying the Mills' rule for the configuration of cyclic allylic alcohols." @default.
• W2039927377 created "2016-06-24" @default.
• W2039927377 creator A5002375618 @default.
• W2039927377 date "1971-01-01" @default.
• W2039927377 modified "2023-10-10" @default.
• W2039927377 title "The influence of allylic oxygen on the π → π* CD of certain chromophores" @default.
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• W2039927377 doi "https://doi.org/10.1016/s0040-4020(01)90774-4" @default.
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