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- W2039928343 abstract "6-Hydroxy-1-fulvencarbaldehyd C7O2H6 (1) kristallisiert in der Raumgruppe Pbca, Z = 8, a = 7.70, b = 14.35, c = 10.95 Å. Die Struktur wurde durch Röntgen- und Neutronenbeugungs-experimente bestimmt. Die Verfeinerungen führten zu konventionellen R-Faktoren von 0.076 bzw. 0.070. Der Abstand zwischen den beiden Sauerstoffatomen ergab sich zu 2.513 (Röntgenbeugung) bzw. 2.550 Å (Neutronenbeugung). Nach den Ergebnissen der Neutronenbeugungsuntersuchungen ist die Wasserstoffbrücke unsymmetrisch, wobei die OH-Abstände 1.343 und 1.214 Å betragen. Der OHO-Winkel wurde zu 171.2° bestimmt. The Intramolecular Hydrogen Bond in 6-hydroxy-1-fulvenecarbaldehyde The title compound 1 (C7O2H6) crystallizes in the space group Pbca, Z = 8, a = 7.70, b = 14.35, c = 10.95 Å. The structure has been determined by X-ray and neutron diffraction experiments. The refinements gave conventional R-factors of 0.076 and 0.070, respectively. The distance between the oxygen atoms was found to be 2.513 (X-ray) and 2.550 Å (neutron diffraction). The neutron diffraction investigation sowed a slightly unsymmetric hydrogen bond with OH distances of 1.343 and 1.214 Å. The OHO angle is 171.2°." @default.
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- W2039928343 date "1975-09-01" @default.
- W2039928343 modified "2023-10-18" @default.
- W2039928343 title "Intramolekulare Wasserstoffbrücke in 6‐Hydroxy‐1‐fulvencarbaldehyd" @default.
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- W2039928343 doi "https://doi.org/10.1002/cber.19751080930" @default.
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