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• W2039934128 endingPage "14" @default.
• W2039934128 startingPage "10" @default.
• W2039934128 abstract "Trianionic pincer ligands are a new class of ligands that constrain three anionic metal–ligand bonds to the meridional plane and are capable of supporting highly reactive metal species exploitable for alkene polymerization. The previously reported NCN3- trianionic pincer CrIV–Me complex [2,6-iPrNCN]CrIV(Me)THF (1), upon activation by triisobutylaluminum (TIBA), catalyzes the polymerization of ethylene. Complex 1 (1 μmol) in the presence of 35 equiv. of TIBA polymerizes ethylene with an activity of 7.02 × 106 g PE(molCr)−1 h−1 (75 °C)." @default.
• W2039934128 created "2016-06-24" @default.
• W2039934128 creator A5037011384 @default.
• W2039934128 creator A5046913706 @default.
• W2039934128 date "2012-07-01" @default.
• W2039934128 modified "2023-09-26" @default.
• W2039934128 title "A neutral trianionic pincer [NCN]CrIV–Me complex as a highly active ethylene polymerization precatalyst" @default.
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• W2039934128 doi "https://doi.org/10.1016/j.jorganchem.2012.03.007" @default.
• W2039934128 hasPublicationYear "2012" @default.

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