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- W2039955390 abstract "BrO radicals were produced by square-wave-modulated photolysis of Br2O3 mixtures and detected in absorption by molecular modulation spectrometry. The spectrum of BrO in the region 296 – 375 nm has been determined from absorption measurements at 0.1 nm intervals and with 0.22 nm resolution. A total of 17 bands in the A 2Π ← X 2Π system were observed and the absorbance in these bands was put on an absolute basis by measurement of the cross section for absorption at the band head of the (v′ = 7) ← (v″ = 0) transition at 338.3 nm. Kinetic studies of BrO in the modulated photolysis system yielded a rate constant for the reaction where k5 = (6.6 ± 1.5) × 10−13 cm3 molecule−1 s−1. k5 showed no significant temperature dependence over the range 278 – 338 K." @default.
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- W2039955390 date "1982-01-01" @default.
- W2039955390 modified "2023-09-27" @default.
- W2039955390 title "Absorption coefficients and kinetics of the BrO radical using molecular modulation" @default.
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- W2039955390 doi "https://doi.org/10.1016/0047-2670(82)80022-1" @default.
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