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- W2039969331 abstract "The behaviour of six members of a homologous series of oxonium ions, C3H7O+CR1R2 (R1, R2 = H or CH3) are discussed. For the two lowest members (R1 = R2 = H) isomerization of the propyl side-chain from n- to iso-structure is possible at energies lower than those required to promote decomposition of either ion. For higher members, rearrangement of the propyl side-chain from n- to iso-structure constitutes the rate-determining step in the dissociation of the ion in question. Extension of the analysis, including a consideration of plausible reactions which are found not to occur, permits estimates to be made for the heats of formation of the intermediates required for rearrangement of the propyl side-chain of C3H7O+CR1R2. It is suggested that these intermediates are stabilized by an ion—dipole interaction between the incipient propyl cation and the potential carbonyl compound, OCR1R2. The magnitude of this stabilization appears to lie in the range 15–25 kcal mol−1." @default.
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- W2039969331 date "1979-01-01" @default.
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- W2039969331 title "Non-concrted unimolecular reactions of ions in the gas-phase: The importance of ion-dipole interactions in carbonium ion isomerizations" @default.
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- W2039969331 doi "https://doi.org/10.1016/0020-7381(79)80017-0" @default.
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