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- W2039970550 abstract "A hydroiodic acid molecule is dissociated by more than four water molecules. Here, the effect of an excess electron on the hexahydated hydroiodic acid where the dissociated structure [H3O+(H2O)5I−] is much more stable than the undissociated one [(H2O)6HI], is investigated. Upon binding an excess electron (e−), the cluster releases a hydrogen radical and forms the stable hexahydrated iodide [(H2O)6I−] when the initial kinetic energy is above ∼200 K, due to the small transition barrier (∼0.5 eV). The system with the hydrogen radical released, [(H2O)6I− + H·], is much more stable than the systems with an excess electron, [(H3O)+{e−(H2O)5}I−] or [e−(H2O)2(H3O)+(H2O)3I−]." @default.
- W2039970550 created "2016-06-24" @default.
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- W2039970550 date "2007-10-10" @default.
- W2039970550 modified "2023-10-16" @default.
- W2039970550 title "Hydrogen detachment of the hexahydrated hydroiodic acid upon attaching an excess electron" @default.
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- W2039970550 doi "https://doi.org/10.1080/00268970701594021" @default.
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