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- W2039996402 abstract "A literature survey shows little consistency in the definitions of the term ‘extensive quantity’ (a.k.a. extensive property) as used in thermodynamics. A majority assumes that extensive quantities are those that are proportional to mass. Taking the mathematical meaning of proportional and taking the ‘mass’ to be that of the system or subsystem, it is shown that the proportionality assumption is only correct for a few extensive quantities under condition of constant composition. A large subset of extensive quantities are completely independent of mass; for most systems extensive quantities are not proportional to mass, but mass is the (extensive) constant of proportionality. The definition by IUPAC, based on the additivity of extensive quantities, is the preferred baseline for discussing this subject. It is noted however, that two types of additivity need to be distinguished and that a few intensive quantities are also additive. This paper leaves several interesting questions open to further scrutiny." @default.
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- W2039996402 date "2014-04-04" @default.
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- W2039996402 title "Extensive quantities in thermodynamics" @default.
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- W2039996402 doi "https://doi.org/10.1088/0143-0807/35/3/035017" @default.
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