Matches in SemOpenAlex for { <https://semopenalex.org/work/W2040000794> ?p ?o ?g. }
- W2040000794 endingPage "4694" @default.
- W2040000794 startingPage "4691" @default.
- W2040000794 abstract "Complex OsH3(SnPh2Cl){[η2-CH2C(CH3)]PiPr2}(PiPr3) (1) undergoes protonation−addition of benzoic acid to give the elongated dihydrogen derivative Os(SnPh2Cl)(κ2-O2CPh)(η2-H2)(PiPr3)2 (2). In solution the tin atom exchanges with the osmium on the chloride ligand by one of the oxygen atoms of the carboxylate group to afford (3). Treatment of the latter with 1.0 equiv of benzoic acid leads to (4). The elongated dihydrogen ligands of 2 and 3 show blocked rotation on the NMR time scale, whereas the hydrogen atoms undergo quantum exchange coupling. The X-ray structures of 3 and 4 are also reported." @default.
- W2040000794 created "2016-06-24" @default.
- W2040000794 creator A5079497892 @default.
- W2040000794 creator A5090236062 @default.
- W2040000794 creator A5091230523 @default.
- W2040000794 date "2006-08-16" @default.
- W2040000794 modified "2023-10-11" @default.
- W2040000794 title "Preparation, X-ray Structures, and NMR Spectra of Elongated Dihydrogen Complexes with Four- and Five-Coordinate Tin Centers" @default.
- W2040000794 cites W1968036379 @default.
- W2040000794 cites W1968634301 @default.
- W2040000794 cites W1968746703 @default.
- W2040000794 cites W1968933530 @default.
- W2040000794 cites W1970662220 @default.
- W2040000794 cites W1971194814 @default.
- W2040000794 cites W1975977201 @default.
- W2040000794 cites W1978705442 @default.
- W2040000794 cites W1985072546 @default.
- W2040000794 cites W1990393638 @default.
- W2040000794 cites W1993528616 @default.
- W2040000794 cites W2001701936 @default.
- W2040000794 cites W2005589556 @default.
- W2040000794 cites W2010289428 @default.
- W2040000794 cites W2012230127 @default.
- W2040000794 cites W2018029751 @default.
- W2040000794 cites W2023518321 @default.
- W2040000794 cites W2023556181 @default.
- W2040000794 cites W2025571784 @default.
- W2040000794 cites W2032186591 @default.
- W2040000794 cites W2037425998 @default.
- W2040000794 cites W2038135062 @default.
- W2040000794 cites W2038740227 @default.
- W2040000794 cites W2040371083 @default.
- W2040000794 cites W2041449206 @default.
- W2040000794 cites W2044984543 @default.
- W2040000794 cites W2058377927 @default.
- W2040000794 cites W2065035168 @default.
- W2040000794 cites W2067416732 @default.
- W2040000794 cites W2067967326 @default.
- W2040000794 cites W2094940620 @default.
- W2040000794 cites W2096627864 @default.
- W2040000794 cites W2101412965 @default.
- W2040000794 cites W2171018965 @default.
- W2040000794 cites W2949802363 @default.
- W2040000794 cites W2952112549 @default.
- W2040000794 cites W993229092 @default.
- W2040000794 doi "https://doi.org/10.1021/om060395g" @default.
- W2040000794 hasPublicationYear "2006" @default.
- W2040000794 type Work @default.
- W2040000794 sameAs 2040000794 @default.
- W2040000794 citedByCount "10" @default.
- W2040000794 countsByYear W20400007942012 @default.
- W2040000794 countsByYear W20400007942016 @default.
- W2040000794 countsByYear W20400007942017 @default.
- W2040000794 countsByYear W20400007942020 @default.
- W2040000794 crossrefType "journal-article" @default.
- W2040000794 hasAuthorship W2040000794A5079497892 @default.
- W2040000794 hasAuthorship W2040000794A5090236062 @default.
- W2040000794 hasAuthorship W2040000794A5091230523 @default.
- W2040000794 hasConcept C116569031 @default.
- W2040000794 hasConcept C121332964 @default.
- W2040000794 hasConcept C1276947 @default.
- W2040000794 hasConcept C145148216 @default.
- W2040000794 hasConcept C155647269 @default.
- W2040000794 hasConcept C161790260 @default.
- W2040000794 hasConcept C170493617 @default.
- W2040000794 hasConcept C178790620 @default.
- W2040000794 hasConcept C185592680 @default.
- W2040000794 hasConcept C2777961443 @default.
- W2040000794 hasConcept C2778074193 @default.
- W2040000794 hasConcept C2778844314 @default.
- W2040000794 hasConcept C2779328170 @default.
- W2040000794 hasConcept C30095370 @default.
- W2040000794 hasConcept C4839761 @default.
- W2040000794 hasConcept C512968161 @default.
- W2040000794 hasConcept C525849907 @default.
- W2040000794 hasConcept C540285154 @default.
- W2040000794 hasConcept C55493867 @default.
- W2040000794 hasConcept C555196967 @default.
- W2040000794 hasConcept C62520636 @default.
- W2040000794 hasConcept C67787023 @default.
- W2040000794 hasConcept C70038680 @default.
- W2040000794 hasConcept C71240020 @default.
- W2040000794 hasConcept C8010536 @default.
- W2040000794 hasConceptScore W2040000794C116569031 @default.
- W2040000794 hasConceptScore W2040000794C121332964 @default.
- W2040000794 hasConceptScore W2040000794C1276947 @default.
- W2040000794 hasConceptScore W2040000794C145148216 @default.
- W2040000794 hasConceptScore W2040000794C155647269 @default.
- W2040000794 hasConceptScore W2040000794C161790260 @default.
- W2040000794 hasConceptScore W2040000794C170493617 @default.
- W2040000794 hasConceptScore W2040000794C178790620 @default.
- W2040000794 hasConceptScore W2040000794C185592680 @default.
- W2040000794 hasConceptScore W2040000794C2777961443 @default.
- W2040000794 hasConceptScore W2040000794C2778074193 @default.
- W2040000794 hasConceptScore W2040000794C2778844314 @default.
- W2040000794 hasConceptScore W2040000794C2779328170 @default.
- W2040000794 hasConceptScore W2040000794C30095370 @default.
- W2040000794 hasConceptScore W2040000794C4839761 @default.