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• W2040009784 abstract "Abstract Several low J microwave transitions of CF 3 NO 2 have been measured under high resolution using a pulsed-nozzle Fourier transform spectrometer. The 14 N quadrupole coupling constants in the inertial axis system have been accurately determined as eQq aa = −0.641(2) MHz, eQq bb = 0.327(6) MHz and eQq cc = 0.314(6) MHz. These measurements were made in the light of renewed interest in the internal rotation dynamics of CF 3 NO 2 . The quadrupole coupling constants provide a probe of the bonding at nitrogen. The measured values are consistent with those known for CH 3 NO 2 , thus providing further evidence for an effective planar geometry of the CNO 2 grouping in CF 3 NO 2 ." @default.
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• W2040009784 date "1996-02-01" @default.
• W2040009784 modified "2023-09-24" @default.
• W2040009784 title "Nitrogen quadrupole coupling in the microwave spectrum of trifluoronitromethane CF3NO2" @default.
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• W2040009784 doi "https://doi.org/10.1016/0022-2860(95)09086-x" @default.
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