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- W2040027365 abstract "A visible-light photoredox synthesis of α-amino amide or α-amino thioamide from N,N-dimethylaniline derivatives and aryl isocyanate or aryl isothiocyanate was developed. Bis[2-(4,6-difluorophenyl)pyridinato-C2,N](picolinato)iridium(III) (FIrpic) was found to be the effective catalyst among six catalysts screened. The reaction involves generation of α-aminoalkyl radicals from tertiary amines, followed by radical addition to the electron-deficient carbon of isocyanate and isothiocyanate." @default.
- W2040027365 created "2016-06-24" @default.
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- W2040027365 date "2013-10-28" @default.
- W2040027365 modified "2023-09-27" @default.
- W2040027365 title "Visible-Light-Mediated Nucleophilic Addition of an α-Aminoalkyl Radical to Isocyanate or Isothiocyanate" @default.
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- W2040027365 doi "https://doi.org/10.1021/ol402573j" @default.
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