FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2040044923> ?p ?o ?g. }

• W2040044923 endingPage "2327" @default.
• W2040044923 startingPage "2308" @default.
• W2040044923 abstract "Ionization-detected absorption spectra of the (100) vibrationally autoionizing states of NO2 have been recorded from double-resonantly prepared N′=1 and N′=7 rotational levels of the 3pσ 2Σ+u (100) Rydberg intermediate state. Photoselection associated with three-color triple-resonant absorption spectroscopy resolves single rotational lines in discrete electronic states that lie above the adiabatic ionization threshold at total energies as high as 78 800 cm−1. Most features observed can be assigned to sσ, dσ, and dπ series converging to the (100) vertical threshold. Identified transitions extend over an interval of principal quantum numbers ranging from 9 to more than 40. A fourth short progression of sharp transitions is assigned as a segment of a g series. The complete spectrum of (100) transitions is modulated in intensity by a sequence of dips that form a series of states, recognized as pσ and pπ, converging to the (110) threshold. Evidence is cited for a mirror-image effect in autoionizing rates, where less-dissociative symmetric-stretch excited states autoionize much more efficiently than above-threshold bending excited states. The spectra span a range from the Hund’s case-b limit to that of case-d coupling. Though extensively obscured by broadening and shifting due to coupling with the ionization continuum and the discrete states of the (110) manifold, resonances in the (100) series show rotational structure consistent with the spectrum of accessible transitions and the variation expected in rotational spacing as Rydberg angular momentum systematically uncouples from the molecular axis. Autoionizing resonances differ significantly in width and line shape, evidencing a systematic variation in the strength with which discrete states are coupled with underlying continua. Fano line shapes indicate a component of direct, virbrationally off-diagonal photoexcitation to the (000) continuum, which interferes with discrete state absorption." @default.
• W2040044923 created "2016-06-24" @default.
• W2040044923 creator A5039323870 @default.
• W2040044923 creator A5082350548 @default.
• W2040044923 creator A5085052462 @default.
• W2040044923 date "1990-08-15" @default.
• W2040044923 modified "2023-10-16" @default.
• W2040044923 title "Triple-resonance spectroscopy of the higher excited states of NO2 : Rovibronic interactions, autoionization, and ℓ-uncoupling in the (100) manifold" @default.
• W2040044923 cites W1531075270 @default.
• W2040044923 cites W1775668542 @default.
• W2040044923 cites W1830482688 @default.
• W2040044923 cites W1969440889 @default.
• W2040044923 cites W1972188647 @default.
• W2040044923 cites W1980052285 @default.
• W2040044923 cites W1985643802 @default.
• W2040044923 cites W1986919716 @default.
• W2040044923 cites W1987887281 @default.
• W2040044923 cites W1987985481 @default.
• W2040044923 cites W1990306753 @default.
• W2040044923 cites W1990666319 @default.
• W2040044923 cites W1992941757 @default.
• W2040044923 cites W1999632030 @default.
• W2040044923 cites W2002191083 @default.
• W2040044923 cites W2006542054 @default.
• W2040044923 cites W2011336383 @default.
• W2040044923 cites W2011769552 @default.
• W2040044923 cites W2023719400 @default.
• W2040044923 cites W2023724409 @default.
• W2040044923 cites W2026247696 @default.
• W2040044923 cites W2026586257 @default.
• W2040044923 cites W2027045192 @default.
• W2040044923 cites W2030619809 @default.
• W2040044923 cites W2037427590 @default.
• W2040044923 cites W2040868919 @default.
• W2040044923 cites W2047575403 @default.
• W2040044923 cites W2049343616 @default.
• W2040044923 cites W2053927248 @default.
• W2040044923 cites W2055240317 @default.
• W2040044923 cites W2055887441 @default.
• W2040044923 cites W2057278741 @default.
• W2040044923 cites W2060460057 @default.
• W2040044923 cites W2061240344 @default.
• W2040044923 cites W2063822703 @default.
• W2040044923 cites W2064011921 @default.
• W2040044923 cites W2064073510 @default.
• W2040044923 cites W2072773098 @default.
• W2040044923 cites W2073348688 @default.
• W2040044923 cites W2074744127 @default.
• W2040044923 cites W2077529100 @default.
• W2040044923 cites W2079072594 @default.
• W2040044923 cites W2084092431 @default.
• W2040044923 cites W2084275505 @default.
• W2040044923 cites W2084765179 @default.
• W2040044923 cites W2088382137 @default.
• W2040044923 cites W2107946726 @default.
• W2040044923 cites W2252746257 @default.
• W2040044923 cites W2317414283 @default.
• W2040044923 cites W2622575233 @default.
• W2040044923 cites W2984980262 @default.
• W2040044923 cites W3024636530 @default.
• W2040044923 cites W4211226287 @default.
• W2040044923 cites W50567789 @default.
• W2040044923 doi "https://doi.org/10.1063/1.459010" @default.
• W2040044923 hasPublicationYear "1990" @default.
• W2040044923 type Work @default.
• W2040044923 sameAs 2040044923 @default.
• W2040044923 citedByCount "40" @default.
• W2040044923 countsByYear W20400449232013 @default.
• W2040044923 crossrefType "journal-article" @default.
• W2040044923 hasAuthorship W2040044923A5039323870 @default.
• W2040044923 hasAuthorship W2040044923A5082350548 @default.
• W2040044923 hasAuthorship W2040044923A5085052462 @default.
• W2040044923 hasConcept C104240894 @default.
• W2040044923 hasConcept C119824511 @default.
• W2040044923 hasConcept C121332964 @default.
• W2040044923 hasConcept C1276947 @default.
• W2040044923 hasConcept C145148216 @default.
• W2040044923 hasConcept C155675718 @default.
• W2040044923 hasConcept C158749347 @default.
• W2040044923 hasConcept C178790620 @default.
• W2040044923 hasConcept C180115280 @default.
• W2040044923 hasConcept C181500209 @default.
• W2040044923 hasConcept C184779094 @default.
• W2040044923 hasConcept C185592680 @default.
• W2040044923 hasConcept C194975256 @default.
• W2040044923 hasConcept C198291218 @default.
• W2040044923 hasConcept C2779446001 @default.
• W2040044923 hasConcept C2779482579 @default.
• W2040044923 hasConcept C2779545503 @default.
• W2040044923 hasConcept C32891209 @default.
• W2040044923 hasConcept C4839761 @default.
• W2040044923 hasConcept C62520636 @default.
• W2040044923 hasConcept C70747811 @default.
• W2040044923 hasConcept C84114770 @default.
• W2040044923 hasConceptScore W2040044923C104240894 @default.
• W2040044923 hasConceptScore W2040044923C119824511 @default.
• W2040044923 hasConceptScore W2040044923C121332964 @default.
• W2040044923 hasConceptScore W2040044923C1276947 @default.

• next