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- W2040047092 abstract "Intermetallics compounds Dy2Fe17Cx (x=1.5,2.0,2.5,2.8) and Tb2Fe17Cx (x=1.5,2.0,2.5) have been successfully prepared by the melt-spinning method. The x-ray-diffraction patterns and the thermomagnetic curves show that they are single phase with the rhombohedral Th2Zn17-type structure, except for Dy2Fe17C2.8 and Tb2Fe17C2.5 which have a small percentage of α-Fe. 57Fe Mössbauer spectra were measured at 12 K and room temperature to study both the magnetic properties of R2Fe17Cx on a local scale and the effect of the interstitial C atom on the Fe atoms. It is found that the effective hyperfine fields of the various Fe sites decrease in the order 6c≳18 f≳18h≳9d. The average effective hyperfine fields Heff at 12 and 293 K do not change much with C concentration x in agreement with the moment of the Fe atoms obtained by magnetic measurements at 1.5 K. It can be concluded that the effect of C is to enhance the exchange interaction between Fe-Fe atoms, which is sensitive to the distance of Fe-Fe atoms. The C has little influence on the moments of Fe atoms." @default.
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- W2040047092 date "1994-11-15" @default.
- W2040047092 modified "2023-09-23" @default.
- W2040047092 title "Mössbauer study of R2Fe17Cx(R=Tb,Dy) as‐quenched intermetallics compounds" @default.
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- W2040047092 doi "https://doi.org/10.1063/1.358175" @default.
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