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• W2040159910 abstract "Abstract Interface geometry and electronic properties of fluorite‐structure NiSi 2 , CoSi 2 and FeSi 2 layers in {111} oriented silicon are studied using density functional methods. Of the atomically flat geometries studied, NiSi 2 is found to preferentially form an interface where the transition‐metal atoms are 7‐fold coordinated, whereas CoSi 2 and γ‐FeSi 2 both adopt 8‐fold coordinations. Schottky‐barrier heights are detailed for the low energy interface structures of the three disilicides. The localisation of states introduced below the Si valence band and in the band‐gap are detailed for infinite systems, with preliminary results for finite layers simulated by dislocation dipoles also being discussed. Our calculations support the view that gap‐states for silicide precipitates are associated with bounding dislocations rather than the planar interfaces. (© 2005 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)" @default.
• W2040159910 created "2016-06-24" @default.
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• W2040159910 date "2005-03-08" @default.
• W2040159910 modified "2023-10-09" @default.
• W2040159910 title "Structural and electronic properties of thin fluorite-structure NiSi₂, CoSi₂and FeSi₂interfaces and precipitates in Si" @default.
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• W2040159910 doi "https://doi.org/10.1002/pssa.200460508" @default.
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