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- W2040176696 abstract "Abstract Enhanced limiting currents for the polarographic reduction of vanadium(V) in NH 3 -NH 4 Cl electrolyte are observed in the presence of nitrite ions. The limiting current is independent of the head of mercury and is proportional to the square root of the nitrite ion concentration. The enhanced current is attributed to the catalytic reduction of nitrite ion, involving the following reactions: V(V) + 3 e → V(II) V(II) + NO 2 − → k V(IV) + reduction of products of NO 2 − V(IV) 4 + 2 e → V(II)" @default.
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- W2040176696 date "1963-09-01" @default.
- W2040176696 modified "2023-09-25" @default.
- W2040176696 title "The catalytic reduction of nitrite ions during polarographic reduction of vanadium(V)" @default.
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- W2040176696 doi "https://doi.org/10.1016/0022-0728(63)80170-9" @default.
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