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• W2040194134 abstract "Multifunctional single and triple-layer films exhibiting flexibility, enhanced modulus and gas barrier properties were developed using a soluble polyamide-imide (PAI) in dimethylacetamide (DMAc) with ammonium-modified montmorillonite (MMT, Cloisite 30B) mineral clay. The drying behavior and associated anisotropy development were determined real-time, using a newly developed real-time measurement system. Out-of-plane birefringence development takes place earlier for thinner neat samples caused primarily by increased depletion rate of solvent. Addition of organoclay content resulted in a decrease in evaporation rate of solvent due to planar orientation of well exfoliated nanoplatelets as shown by TEM images and WAXS. This is in agreement with the out-of-plane anisotropy development observed during drying. Beyond a critical solid wt%, out-of-plane birefringence started to increase earlier with organoclay addition. In the case of multi-layer organoclay reinforced PAI films, the drying behavior of each individual layer was tracked and a complementary drying model is proposed. Planar orientation of nanoplatelets resulted in high helium-barrier properties." @default.
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• W2040194134 date "2014-08-01" @default.
• W2040194134 modified "2023-10-16" @default.
• W2040194134 title "Enhanced gas barrier and mechanical properties in organoclay reinforced multi-layer poly(amide-imide) nanocomposite film" @default.
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• W2040194134 doi "https://doi.org/10.1016/j.polymer.2014.06.058" @default.
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