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- W2040203556 abstract "The photochemistry of 3-methyl- and 3-isopropyl-3-ferrocenylcyclopropenes ( 10 and 11 ) has been studied. Upon triplet excitation (sensitized irradiation) both cyclopropenes are dimerized to a tricyclohexane dimers whereas in the singlet state (direct irradiation) cyclopropene 10 is converted to 3-ferrocenyl-3-methylidenepropyne and trans -2-ferrocenyl-2-butene indicating that there is an intermediate vinyl carbene. Cyclopropene 11 is converted to 1-ferrocenyl-4,4-dimethylcyclobutene. Direct irradiation of the mixture of 11 with 2-ferrocenyl-3-methyl-1-butene leads to the formation of 1,3-diferrocenyl-6,6-dimethyl-3-isopropenylcyclohexene ( 24 ). A possible reaction pathway via intermediate radicals is discussed. X-ray structural data are presented for 3,6-diferrocenyl-3,6-diisopropyltricyclo[3.1.0.0. 2,4 ]hexane and compound 24 ." @default.
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- W2040203556 date "2000-06-01" @default.
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- W2040203556 title "Photolysis of 3-methyl- and 3-isopropyl-3-ferrocenylcyclopropenes" @default.
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- W2040203556 doi "https://doi.org/10.1016/s0022-328x(00)00264-3" @default.
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