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- W2040204551 abstract "A millimeter-wave spectrometer having a sensitivity of 4 × 10−10 cm−1 in the 2-mm region has been constructed for observation of extremely weak millimeter-wave spectra of gases. It has been used to measure J → J, K = 0 ← 3 transitions in PH3 and J → J, K = 0 ← 3 as well as K = ±1 ← ±4 transitions in PD3. The B0 and C0 spectral constants (in MHz) are: for PH3, B0 = 133 480.15 ± 0.12 and C0 = 117 488.85 ± 0.16; for PD3, B0 = 69 471.10 ± 0.03 and C0 = 58 974.37 ± 0.05. The effective ground-state values obtained for the bond angle and bond length are: for PH3, r0 (Å) = 1.4200 and α0(o) = 93.345; for PD3, r0 (Å) = 1.4176 and α0(o) = 93.359. The corresponding zero-point-average values were calculated to be: for PH3, rz (Å) = 1.42699 ± 0.0002 and αz(o) = 93.2287; for PD3, rz (Å) = 1.42265 ± 0.0001 and αz(o) = 93.2567 ± 0.004. For both species, the equilibrium values are re (Å) = 1.41159 ± 0.0006 and αe(o) = 93.328 ± 0.02." @default.
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- W2040204551 date "1977-08-01" @default.
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- W2040204551 title "“Forbidden” rotational spectra of symmetric-top molecules: PH3 and PD3" @default.
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- W2040204551 doi "https://doi.org/10.1016/0022-2852(77)90211-9" @default.
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