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• W2040205611 abstract "Li2MTi3O8 (M=Co, Co0.5Cu0.5) spinels were successfully synthesized by a simple high temperature solid-state method. Both Li2CoTi3O8 and Li2Co0.5Cu0.5Ti3O8 show a cubic structure with P4332 space group. Rietveld refinement result reveals that Li2CoTi3O8 can be described as [Li0.5Co0.45]tet[(Li0.5Co0.05)Ti1.5]octO4. After Cu2+ doping, half Co2+ in [Li0.5Co0.45]tet[(Li0.5Co0.05)Ti1.5]octO4 is replaced by Cu2+ to form a complex spinel titanate [Li0.5Co0.225Cu0.225]tet[(Li0.5Co0.025Cu0.025)Ti1.5]octO4 without structural changes. As lithium storage material, Li2CoTi3O8 shows poor electrochemical performance at a current density of 100 mA g−1 in the potential window of 0.0–3.0 V. After 50 cycles, Li2CoTi3O8 maintains a reversible capacity of 42 mAh g−1 with a low capacity retention of 19.5%. For comparison, Li2Co0.5Cu0.5Ti3O8 can deliver a higher reversible capacity of 98 mAh g−1 after 50 cycles with a capacity retention of 44.4%. It suggests that copper ion doing can effectively enhance the capability for electrochemical lithium storage in Li2CoTi3O8." @default.
• W2040205611 created "2016-06-24" @default.
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• W2040205611 date "2014-09-01" @default.
• W2040205611 modified "2023-09-23" @default.
• W2040205611 title "Solid state synthesis of Li2Co0.5Cu0.5Ti3O8 and Li2CoTi3O8 and their comparative lithium storage properties" @default.
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• W2040205611 doi "https://doi.org/10.1016/j.ceramint.2014.05.083" @default.
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