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• W2040205965 endingPage "883" @default.
• W2040205965 startingPage "876" @default.
• W2040205965 abstract "The microsolvation of the suberate dianion, -O2C(CH2)6CO2-, with two separate charge centers was studied by photoelectron spectroscopy and molecular dynamics simulation one solvent molecule at a time for up to 20 waters. It is shown that the two negative charges are solvated in the linear suberate alternately. As the solvent number increases, the negative charges are screened and a conformation change occurs at 16 waters, where the cooperative hydrogen bonding of water is large enough to overcome the Coulomb repulsion and pull the two negative charges closer through a water bridge. This conformation change, revealed both from the experiment and from the simulation, is a manifestation of the hydrophilic and hydrophobic forces at the molecular level." @default.
• W2040205965 created "2016-06-24" @default.
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• W2040205965 date "2004-01-03" @default.
• W2040205965 modified "2023-10-17" @default.
• W2040205965 title "Solvent-Mediated Folding of a Doubly Charged Anion" @default.
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• W2040205965 doi "https://doi.org/10.1021/ja038108c" @default.
• W2040205965 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/14733563" @default.
• W2040205965 hasPublicationYear "2004" @default.
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