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- W2040221344 abstract "The deexcitation of HCl(v) by HCl(0) for v=1–4 is shown to undergo vibration-to-vibration (V–V) energy exchange with the transfer of the energy mismatch ΔE through rotation (R) and translation (T). When v is small, the translational motion plays a major role in transferring ΔE, but when v is large, the rotational motion is of major importance in supplying ΔE. The sum of V–V, T and V–V, R contributions are in reasonable agreement with observed data at 300 K. For v≳4, the V–V mechanism appears to underestimate deexcitation probabilities seriously." @default.
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- W2040221344 title "Vibration‐to‐vibration energy transfer in the deexcitation of HCl(v) by HCl(0): Role of the rotational and translational motions" @default.
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- W2040221344 doi "https://doi.org/10.1063/1.444778" @default.
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