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• W2040229494 endingPage "9075" @default.
• W2040229494 startingPage "9068" @default.
• W2040229494 abstract "The reactivity of divanadium-substituted silicotungstate, γ-H2SiV2W10O404- (I), with hydroxo compounds of alcohols, carboxylic acids, and water is reported. The reaction of the bis(μ-hydroxo) divanadium site in I with primary alcohols and formic acid smoothly proceeds to form corresponding monoesters and monoformate, respectively, and the crystal structures of the monomethyl and monoethyl esters and the monoformate of I are determined. The oxygen exchange between the hydroxo group and water proceeds easily. On the other hand, bulky compounds of 2-propanol, tert-butyl alcohol, and acetic acid hardly react with the bis(μ-hydroxo) divanadium site (equilibrium constant < 0.01) because of the steric crowding between the methyl groups and the polyoxometalate framework." @default.
• W2040229494 created "2016-06-24" @default.
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• W2040229494 creator A5053881651 @default.
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• W2040229494 date "2005-10-12" @default.
• W2040229494 modified "2023-10-01" @default.
• W2040229494 title "Reactivity of Bis(μ-hydroxo) Divanadium Site in γ-H₂SiV₂W₁₀O₄₀⁴^- with Hydroxo Compounds" @default.
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• W2040229494 doi "https://doi.org/10.1021/ic051163x" @default.
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