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- W2040233859 abstract "O polysaccharides (OPS) of the lipopolysaccharides (LPS) of Pseudomonas syringae pathovar tomato GSPB 483 and pathovar maculicola IMV 381 were studied by 1H-NMR and 13C-NMR spectroscopy, including two-dimensional COSY, rotating-frame NOE spectroscopy (ROESY), and H-detected 1H,13C heteronuclear multiple-quantum coherence (HMQC) experiments. The OPS from both strains were shown to be chemically identical. Two structurally different types of repeating units (O repeats 1 and 2) were elucidated in each OPS. The minor O repeat is a pentasaccharide having the structure 2. The same structure has been reported earlier for some other OPS of P. syringae. The major O repeat is a hexasaccharide with the novel structure 1 which is distinguished from 2 by the presence of the second lateral residue of 3-acetamido-3,6-dideoxy- D-galactose ( D-Fuc3NAc) and by a different position of substitution of one of the L-rhamnose (Rha) residues in the backbone. α- D-Fucp3NAc α- D-Fucp3NAc 1 1 ↓↓ 3 3 ←2)-α- L-Rhap-(1←2)-α- L-Rhap-(1←3)-α- L-Rhap-(1←3)-α- L-Rhap-(1←1 α- D-Fucp3NAc 1 ↓ 3 ←2)-α- L-Rhap-(1←3)-α- L-Rhap-(1←3)-α- L-Rhap-(1←3)-α- L-Rhap-(1←2 Structural and serological diversity of OPS of strains belonging to P. syringae pv. tomato and pv. maculicola and phylogenetic relatedness of the strains are discussed." @default.
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- W2040233859 date "1998-12-01" @default.
- W2040233859 modified "2023-10-16" @default.
- W2040233859 title "Structure of the O polysaccharide and immunochemical relationships between the lipopolysaccharides of Pseudomonas syringae pathovar tomato and pathovar maculicola" @default.
- W2040233859 doi "https://doi.org/10.1046/j.1432-1327.1998.2580657.x" @default.
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