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- W2040247414 abstract "The relationship between ideal copolymerization behavior and the nature of reactive species in butyllithium (n-BuLi) initiated anionic copolymerization of styrene (St)- butadiene (Bd) in nonpolar solvent has been discussed.The monomer reactivity ratios (m.r.r.) for various reactive species were evaluated by kinetic study and statistical approach (using 13C NMR data) in St-Bd anionic copolymerization system with THF as polar additive. The Markovian mechanisms for different propagating reactions in this complex copolymerizing system have been postulated.Furthermore, “pseudo” zero order Markovian mechnism could be sophisticatedly established in the n-BuLi/tertiary amyloxy potassium (t-AmOK)/THF initiated St-Bd copolymerization system, provided that the apparent rate constants of both monomers are equal. Thus, by adjusting the ratio of K/Li and THF/Li, copolymers with composition almost identical to the ratio of initial monomer feed composition at different stages of conversion could be obtained." @default.
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- W2040247414 date "1994-08-01" @default.
- W2040247414 modified "2023-09-25" @default.
- W2040247414 title "Some aspects of anionic butadiene copolymerization" @default.
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- W2040247414 doi "https://doi.org/10.1002/masy.19940850119" @default.
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