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- W2040247641 abstract "Heats of formation of α and γ aluminium hydrides have been measured by means of a scanning Calvet microcalorimeter: Thermal dissociation of AIH3γ shows an exothermic effect associated with hydrogen evolution followed by the endothermic decomposition of AIH3α. On the basis of the quantities of gas evolved, a solvent-free aluminium alanate structure, AI (AIH2)3, is proposed for AIH3γ. Les enthalpics de formation des 2 formes cristallines α et 7 dc l'hydrure d'aluminium ont été déterminées au moyen d'un microcalorimétre Calvet: Le décomposition thermique de AIH3γ s'accompagne d'un effet exothermique avec un départ d'hydrogéne correspondant au passage á AIH3α puis d'un effet endothermique dú á la décomposition de la phase α formée. La comparaison des quantités d'hyrogéne dégagées permet de proposer pour AIH3γ une structure alanate AI(AIH3)3." @default.
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- W2040247641 date "1978-12-01" @default.
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- W2040247641 title "Determination des constantes thermodynamiques des hydrures simples et complexes de l'aluminium. III. Enthalpie de formation de AIH3α ET AIH3γ" @default.
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- W2040247641 doi "https://doi.org/10.1016/0040-6031(78)85035-7" @default.
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