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- W2040247939 abstract "The rotational spectra of two conformations of 3-chloro-propanol were observed for the four possible Cl(35)Cl(37) and HD isotopic species. For both conformations the oxygen atom is gauche with respect to the C2C3 bond and the hydroxyl hydrogen is trans with respect to the C2C1 bond. In one conformation (T) the chlorine is trans with respect to C1C2 and it is gauche in the other form (G). The ground state of the G form is about 0.7 kcal/mole more stable than that of the T form. A discussion is given about the failure to observe the H bond species. The most likely reason is the too close approach of Cl and O in this hypothetical configuration. The quadrupole coupling constants were obtained for the G form. The rotational spectra of five excited states of the T form and of one excited state of the G species were measured. Partial r0 and rs structures are given." @default.
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- W2040247939 date "1982-11-01" @default.
- W2040247939 modified "2023-10-14" @default.
- W2040247939 title "Rotational isomerism in 3-chloro-1-propanol from the microwave spectrum" @default.
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- W2040247939 doi "https://doi.org/10.1016/0022-2852(82)90219-3" @default.
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