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• W2040249675 endingPage "1334" @default.
• W2040249675 startingPage "1327" @default.
• W2040249675 abstract "The self-assembly of various anions (e.g., thiocyanate, nitrite/nitrate, sulfite/sulfate, tetrahalometallates, etc.) with prototypical π-acids (consisting of cyano- and nitrosubstituted pyrazine and benzene, as well as tetracyanoethylene) occurs rapidly and selectively to yield a series of novel one-dimensional structures. The wire-like molecular chains all consist of parallel stacks of π-acids and alternate anions of different sizes and shapes that establish the dihedral angles α and φ sufficient to define these unique structures. Analogy of such linear arrays to nanoscopic wires is reinforced by the protective sheath of countercations that are completely arrayed around the linear cores. The critical feature of these efficient self-assemblies is shown to derive from anion/π-recognitions via charge-transfer forces between the electron-rich anions acting as electron donors and the electron-poor π-acids acting as electron acceptors to spontaneously generate synthons according to Mulliken theory." @default.
• W2040249675 created "2016-06-24" @default.
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• W2040249675 creator A5030343286 @default.
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• W2040249675 date "2008-02-26" @default.
• W2040249675 modified "2023-10-16" @default.
• W2040249675 title "Anion Recognitions via Cocrystallizations with Organic π-Acids in the Efficient Self-Assembly of Nanoscopic One-Dimensional Molecular Chains (Wires)" @default.
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• W2040249675 doi "https://doi.org/10.1021/cg701138n" @default.
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