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- W2040258625 abstract "The synthesis of N-glycans carrying the ‘bisecting’ GlcNAc modification is difficult due to steric hindrance at the central β-mannoside. A facile introduction of a ‘bisecting’ GlcNAc residue was accomplished by using an excess of a glucosaminyl fluoride. After deprotection of the resulting octasaccharide a 6-aminohexanoyl spacer was attached. Enzymatic elongation of the carbohydrate chains using three different glycosyltransferases gave full length ‘bisecting’ N-glycans of the complex type terminating with galactose, α-2,6 or α-2,3 linked sialic acid." @default.
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- W2040258625 date "2000-06-01" @default.
- W2040258625 modified "2023-10-17" @default.
- W2040258625 title "Chemoenzymatic synthesis of deca and dodecasaccharide N-glycans of the ‘bisecting’ type" @default.
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- W2040258625 doi "https://doi.org/10.1016/s0040-4039(00)00698-5" @default.
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