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- W2040267982 abstract "In the present work di-urethane cross-linked poly(oxyethylene) (POE)/siloxane hybrids (di-urethanesils) incorporating magnesium triflate (Mg(CF3SO3)2) with 100 ≥ n ≥ 2 (where n, composition, is the molar ratio of oxyethylene repeat units per Mg2+ ion) have been characterized by Fourier transform infrared and Raman spectroscopy to elucidate the Mg2+/POE, Mg2+/urethane, Mg2+/CF3SO3− and hydrogen bonding interactions. The Mg2+ ions bond to POE chains and to the carbonyl oxygen atoms of the urethane linkages over the whole range of salt content studied. A crystalline POE/Mg(CF3SO3)2 complex of unknown stoichiometry is formed at n = 5. “Free” and weakly coordinated CF3SO3− ions are present in all the materials examined. Contact ion pairs emerge at n ≤ 20 and higher ionic aggregates appear at n ≤ 5." @default.
- W2040267982 created "2016-06-24" @default.
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- W2040267982 date "2011-11-01" @default.
- W2040267982 modified "2023-09-26" @default.
- W2040267982 title "FT-IR and FT-Raman spectroscopy study of di-urethanesil hybrids doped with Mg(CF3SO3)2" @default.
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- W2040267982 doi "https://doi.org/10.1016/j.vibspec.2011.07.004" @default.
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