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- W2040285250 abstract "4-(Carboxymethyl)phenylalanine (2) and its α,α-difluoro homologue 4-(carboxydifluoromethyl)phenylalanine (3) have been described as phosphotyrosyl mimetics. Herein we report the synthesis of N-Fmoc 4-(O-tert-butyl carboxymethyl)phenylalanine (4) and N-Fmoc 4-(O-tert-butyl carboxydifluoromethyl)phenylalanine (5) in high enantiomeric purity. These analogues bear orthogonal protection suitable for the preparation of inhibitors directed against a variety of signal transduction pathways, including SH2 and PTP domains and protein-tyrosine phosphatases." @default.
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- W2040285250 date "1999-03-01" @default.
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- W2040285250 title "Synthesis of Fmoc-protected 4-carboxydifluoromethyl-L-phenylalanine: A phosphotyrosyl mimetic of potential use for signal transduction studies" @default.
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- W2040285250 doi "https://doi.org/10.1016/s0040-4020(99)00076-9" @default.
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