Matches in SemOpenAlex for { <https://semopenalex.org/work/W2040290838> ?p ?o ?g. }
- W2040290838 endingPage "435" @default.
- W2040290838 startingPage "424" @default.
- W2040290838 abstract "Carbon xerogels with various pore textures were functionalized by HNO3or air to increase the numberof acidic functions on their surface. These oxidized materials were systematically thermally treated toremove the unstable functions. Analyses indicated that the air treatment was the most efficient becausethe functions created are more numerous, more stable and homogeneously distributed within the sup-port. These surface oxygenated groups were used as anchors for the covalent grafting of the complex[Pd(OAc)2(Et2NH)2] through a ligand exchange mechanism. Activation was carried out thermally to pro-duce supported Pd nanoparticles and led to less sintering compared to a control catalyst prepared on anunmodified support. Catalysts were tested in two different catalytic reactions, namely lactose oxidationand hydrolytic oxidation of cellobiose. The former requires as few surface functions as possible whilethe latter demands a bifunctional catalyst for hydrolysis followed by oxidation. The oxidation of lactosewas more efficient with the catalyst prepared on an unmodified carbon xerogel. On the opposite, thehydrolytic oxidation of cellobiose worked the best with a low loaded catalyst prepared on a functional-ized support, which provided the acidic functions needed for hydrolysis. Moreover, 100% selectivity forgluconic acid was achieved." @default.
- W2040290838 created "2016-06-24" @default.
- W2040290838 creator A5035723985 @default.
- W2040290838 creator A5042114363 @default.
- W2040290838 creator A5053575582 @default.
- W2040290838 creator A5066275852 @default.
- W2040290838 creator A5068061911 @default.
- W2040290838 creator A5081064244 @default.
- W2040290838 date "2014-04-01" @default.
- W2040290838 modified "2023-09-26" @default.
- W2040290838 title "Functionalization of carbon xerogels for the preparation of palladium supported catalysts applied in sugar transformations" @default.
- W2040290838 cites W1497567690 @default.
- W2040290838 cites W1964224703 @default.
- W2040290838 cites W1965507023 @default.
- W2040290838 cites W1967067055 @default.
- W2040290838 cites W1968733293 @default.
- W2040290838 cites W1972774471 @default.
- W2040290838 cites W1974720414 @default.
- W2040290838 cites W1978500700 @default.
- W2040290838 cites W1978535220 @default.
- W2040290838 cites W1979584058 @default.
- W2040290838 cites W1982632848 @default.
- W2040290838 cites W1988775398 @default.
- W2040290838 cites W1992435289 @default.
- W2040290838 cites W1993365679 @default.
- W2040290838 cites W1995737205 @default.
- W2040290838 cites W1999657313 @default.
- W2040290838 cites W2003847580 @default.
- W2040290838 cites W2010332779 @default.
- W2040290838 cites W2011638789 @default.
- W2040290838 cites W2012311804 @default.
- W2040290838 cites W2012348150 @default.
- W2040290838 cites W2013591720 @default.
- W2040290838 cites W2017714800 @default.
- W2040290838 cites W2018122539 @default.
- W2040290838 cites W2018669316 @default.
- W2040290838 cites W2020394480 @default.
- W2040290838 cites W2022770744 @default.
- W2040290838 cites W2024234296 @default.
- W2040290838 cites W2024620475 @default.
- W2040290838 cites W2027041983 @default.
- W2040290838 cites W2027353810 @default.
- W2040290838 cites W2030472247 @default.
- W2040290838 cites W2034273164 @default.
- W2040290838 cites W2036117640 @default.
- W2040290838 cites W2037565019 @default.
- W2040290838 cites W2039663055 @default.
- W2040290838 cites W2040725928 @default.
- W2040290838 cites W2040864537 @default.
- W2040290838 cites W2044520840 @default.
- W2040290838 cites W2045958537 @default.
- W2040290838 cites W2047159711 @default.
- W2040290838 cites W2047811695 @default.
- W2040290838 cites W2050570298 @default.
- W2040290838 cites W2061974346 @default.
- W2040290838 cites W2080962199 @default.
- W2040290838 cites W2083951913 @default.
- W2040290838 cites W2084634636 @default.
- W2040290838 cites W2085769368 @default.
- W2040290838 cites W2085991080 @default.
- W2040290838 cites W2086176033 @default.
- W2040290838 cites W2091480062 @default.
- W2040290838 cites W2094946076 @default.
- W2040290838 cites W2112947303 @default.
- W2040290838 cites W2116370970 @default.
- W2040290838 cites W2119076684 @default.
- W2040290838 cites W2126518796 @default.
- W2040290838 cites W2136314201 @default.
- W2040290838 cites W2144434264 @default.
- W2040290838 cites W2150860470 @default.
- W2040290838 cites W2152970122 @default.
- W2040290838 cites W2161520778 @default.
- W2040290838 cites W2170072021 @default.
- W2040290838 cites W2205259046 @default.
- W2040290838 cites W2321229683 @default.
- W2040290838 cites W2952158875 @default.
- W2040290838 doi "https://doi.org/10.1016/j.apcatb.2013.11.028" @default.
- W2040290838 hasPublicationYear "2014" @default.
- W2040290838 type Work @default.
- W2040290838 sameAs 2040290838 @default.
- W2040290838 citedByCount "18" @default.
- W2040290838 countsByYear W20402908382015 @default.
- W2040290838 countsByYear W20402908382016 @default.
- W2040290838 countsByYear W20402908382017 @default.
- W2040290838 countsByYear W20402908382018 @default.
- W2040290838 countsByYear W20402908382019 @default.
- W2040290838 countsByYear W20402908382020 @default.
- W2040290838 countsByYear W20402908382021 @default.
- W2040290838 countsByYear W20402908382022 @default.
- W2040290838 crossrefType "journal-article" @default.
- W2040290838 hasAuthorship W2040290838A5035723985 @default.
- W2040290838 hasAuthorship W2040290838A5042114363 @default.
- W2040290838 hasAuthorship W2040290838A5053575582 @default.
- W2040290838 hasAuthorship W2040290838A5066275852 @default.
- W2040290838 hasAuthorship W2040290838A5068061911 @default.
- W2040290838 hasAuthorship W2040290838A5081064244 @default.
- W2040290838 hasConcept C104779481 @default.
- W2040290838 hasConcept C115537861 @default.