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- W2040295990 abstract "The triple decker complex [{(η 5 -Cp*)Co} 2 -μ-{η 4 : η 4 -toluene}] 1b exhibits an unusual reactivity towards a variety of organic ligands, 1b reacts with CO, ethene, butadiene, H 2 , Al 2 O 3 , hexafluorobenzene, 1.5 Cod, 2-butyne, phenanthrene, naphthalene and the dinuclear Ni cluster [{(η 5 -Cp)NiP(C 2 H 5 ) 3 } 2 ] to form mainly mononuclear organocobalt complexes. Reaction of 1b with NO and the diazoalkanes di-t-butyl-diazomethane and 2-diazo-1,1′,3,3′-tetramethylcyclohexane results in the formation of the dinuclear complexes [{(η 5 -Cp*)CoNO} 2 ], [{(η 5 -Cp*)(di-t-butyl-diazomethane)Co} 2 ] and [{(η 5 -Cp*)(2-diazo-1,1′,3,3′-tetramethylcyclohexane) Co} 2 ], respectively. In the reaction of 1b with elemental sulfur the formation of a tetranuclear Co-sulfide cluster is observed. In the majority of the reactions studied, l b looses its toluene ligand already at room temperature indicating an unusual high and hitherto unprecedented reactivity of an arene triple decker complex." @default.
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- W2040295990 date "1995-07-01" @default.
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- W2040295990 title "Reactivity of an Arene Cobalt Triple Decker Complex Towards Various Ligands. Facile Arene Displacement in [Bis{( η<sup>5</sup>-pentamethylcyclopentadienyl)cobalt}-μ-{η<sup>4</sup>: η<sup>4</sup>-toluene}]" @default.
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