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• W2040303322 abstract "General techniques are presented for factorizing the multispin form of quantum-Liouville equation for spin evolution under scalar coupling. Projection superoperator formalisms are derived that allow partitioning of the spherical basis, |kgv〉〉, components of Liouville space under the group algebra of the inner direct product, Sn[x]Sn …, for multicluster spin systems. A special feature of weakly coupled spin systems allows labelling with respect to the spherical components, q, qA and qx, in addition to irreducible representations under the permutation group, Sn to provide multiple partitioning, denoted by nμq,qx. The importance of permutation symmetry with its related invariance hierarchy is stressed by presenting the discrete subdomain dimensionality structure associated with the [AMX]2 and [A]2[X]4 spin-12 systems under the groups S2 and S4 = D2f, respectively. The inclusion of the effects of finite pulse widths, applicable to pulse experiments involving weakly coupled heteronuclear [AX]n, spin systems, leads to the realizations of further dimensionality reductions and simplifications. The invariance properties of certain quadrupolar, [Q]n spin clusters under Sn are considered in the context of [AQ]2-type systems with general applications to the “particle” subspectral approach." @default.
• W2040303322 created "2016-06-24" @default.
• W2040303322 creator A5052787408 @default.
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• W2040303322 date "1986-08-01" @default.
• W2040303322 modified "2023-10-16" @default.
• W2040303322 title "Symmetry-adapted bases and projection superoperators of multiquantum NMR under the groups 2[x]2 and 4[x]2" @default.
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• W2040303322 doi "https://doi.org/10.1016/0022-2364(86)90214-3" @default.
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