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• W2040304034 abstract "Abstract The decarbonylation of the tropone radical cation has been studied by time-resolved photoionization mass spectrometry (TPIMS) and time-resolved ion momentum spectrometry (TRIMS). Experimental photoionization efficiency curves at t = 6 μs and 2 ms were modelled by RRKM/QET calculations. The critical energy of activation ( E 0 ) was determined to be 83.9 ± 5 kJ mol . The reactant C 7 H 6 O + is less stable than the products C 6 H 6 + +CO, and the reaction possesses a reverse activation energy of 128 kJ mol which results in a large kinetic energy release." @default.
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• W2040304034 date "1987-04-01" @default.
• W2040304034 modified "2023-09-27" @default.
• W2040304034 title "Time-dependent mass spectra and breakdown graphs: The decarbonylation of tropone11This is part IX of a series in which ref. [7] is part VIII." @default.
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• W2040304034 doi "https://doi.org/10.1016/0009-2614(87)87302-5" @default.
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