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• W2040306724 abstract "Au nanoparticles (NPs) from 2.1 to 6.2 nm and Pt NPs in 2–3 nm were supported on the amide functional silica (SiO2-N). The effect of particle size on the catalytic activity was investigated by the 1,3-butadiene hydrogenation reaction. Based on thermal conductivity detector (TCD) signal, the reaction is size-dependent. The highest turnover frequency (TOF) occurs at a particle size of ~ 3 nm, while the Pt NPs are inactive (0.001 s− 1). It indicates that Au based catalysts are more active than supported Pt based catalyst at very low temperature. In addition, the σ-bonded species on Au particles have been characterized by in situ Fourier transform infrared (FT-IR) spectroscopy. It means that the chemical adsorbate–substrate interaction is strong at low temperature." @default.
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• W2040306724 date "2015-07-01" @default.
• W2040306724 modified "2023-10-07" @default.
• W2040306724 title "Hydrogenation of 1,3-butadiene over Au and Pt/SiO2-N catalysts at low temperature" @default.
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• W2040306724 doi "https://doi.org/10.1016/j.catcom.2015.04.007" @default.
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