Matches in SemOpenAlex for { <https://semopenalex.org/work/W2040332425> ?p ?o ?g. }
Showing items 1 to 88 of
88
with 100 items per page.
- W2040332425 endingPage "312" @default.
- W2040332425 startingPage "303" @default.
- W2040332425 abstract "The reaction of cis-(CO)4Fe[Si(CH3)3]2 (I) with CH3OSi(CH3)3 and C6H5CH2-OSi(CH3)3 at 80°C affords good yields of [(CH3)3Si]2O and the deoxygenation products RSi(CH3)3 (R CH3, C6H5CH2). These reactions are proposed to occur via (CO)4Fe(R)Si(CH3)3 intermediates. This is supported by the observed formation of cis-(CO)4Fe(CH3)Si(CH3)3 (II) during the more rapid reaction of I with (CH3)2O; subsequent (CH3)4Si elimination occurs. With (C6H5CH2)2O, I reacts at 80°C to yield C6H5CH2Si(CH3)3 and C6H5CH2OSi(CH3)3 as primary products. With C6H5CH2OCH3, I effects regioselective benzyloxygen bond cleavage." @default.
- W2040332425 created "2016-06-24" @default.
- W2040332425 creator A5045143638 @default.
- W2040332425 creator A5064454551 @default.
- W2040332425 date "1981-05-01" @default.
- W2040332425 modified "2023-10-16" @default.
- W2040332425 title "New deoxygenative transformations; reactions of (CO)4Fe[Si(CH3)3]2 with acyclic ethers" @default.
- W2040332425 cites W1554778425 @default.
- W2040332425 cites W1973332435 @default.
- W2040332425 cites W1989772338 @default.
- W2040332425 cites W1992091920 @default.
- W2040332425 cites W1992233141 @default.
- W2040332425 cites W1995745808 @default.
- W2040332425 cites W1997312942 @default.
- W2040332425 cites W2001207241 @default.
- W2040332425 cites W2005400620 @default.
- W2040332425 cites W2026884893 @default.
- W2040332425 cites W2075834825 @default.
- W2040332425 cites W2110107199 @default.
- W2040332425 cites W2312686629 @default.
- W2040332425 cites W2337547816 @default.
- W2040332425 cites W3136607177 @default.
- W2040332425 cites W3137566290 @default.
- W2040332425 cites W4244518286 @default.
- W2040332425 cites W4256300105 @default.
- W2040332425 doi "https://doi.org/10.1016/s0022-328x(00)80889-x" @default.
- W2040332425 hasPublicationYear "1981" @default.
- W2040332425 type Work @default.
- W2040332425 sameAs 2040332425 @default.
- W2040332425 citedByCount "12" @default.
- W2040332425 countsByYear W20403324252019 @default.
- W2040332425 countsByYear W20403324252023 @default.
- W2040332425 crossrefType "journal-article" @default.
- W2040332425 hasAuthorship W2040332425A5045143638 @default.
- W2040332425 hasAuthorship W2040332425A5064454551 @default.
- W2040332425 hasConcept C121332964 @default.
- W2040332425 hasConcept C127413603 @default.
- W2040332425 hasConcept C134121241 @default.
- W2040332425 hasConcept C155647269 @default.
- W2040332425 hasConcept C161790260 @default.
- W2040332425 hasConcept C175156509 @default.
- W2040332425 hasConcept C178790620 @default.
- W2040332425 hasConcept C185592680 @default.
- W2040332425 hasConcept C187320778 @default.
- W2040332425 hasConcept C2779778602 @default.
- W2040332425 hasConcept C2991944050 @default.
- W2040332425 hasConcept C3044715 @default.
- W2040332425 hasConcept C43369102 @default.
- W2040332425 hasConcept C540031477 @default.
- W2040332425 hasConcept C59759590 @default.
- W2040332425 hasConcept C97355855 @default.
- W2040332425 hasConceptScore W2040332425C121332964 @default.
- W2040332425 hasConceptScore W2040332425C127413603 @default.
- W2040332425 hasConceptScore W2040332425C134121241 @default.
- W2040332425 hasConceptScore W2040332425C155647269 @default.
- W2040332425 hasConceptScore W2040332425C161790260 @default.
- W2040332425 hasConceptScore W2040332425C175156509 @default.
- W2040332425 hasConceptScore W2040332425C178790620 @default.
- W2040332425 hasConceptScore W2040332425C185592680 @default.
- W2040332425 hasConceptScore W2040332425C187320778 @default.
- W2040332425 hasConceptScore W2040332425C2779778602 @default.
- W2040332425 hasConceptScore W2040332425C2991944050 @default.
- W2040332425 hasConceptScore W2040332425C3044715 @default.
- W2040332425 hasConceptScore W2040332425C43369102 @default.
- W2040332425 hasConceptScore W2040332425C540031477 @default.
- W2040332425 hasConceptScore W2040332425C59759590 @default.
- W2040332425 hasConceptScore W2040332425C97355855 @default.
- W2040332425 hasIssue "3" @default.
- W2040332425 hasLocation W20403324251 @default.
- W2040332425 hasOpenAccess W2040332425 @default.
- W2040332425 hasPrimaryLocation W20403324251 @default.
- W2040332425 hasRelatedWork W2053825085 @default.
- W2040332425 hasRelatedWork W2057279800 @default.
- W2040332425 hasRelatedWork W2097014657 @default.
- W2040332425 hasRelatedWork W2179557952 @default.
- W2040332425 hasRelatedWork W2391030496 @default.
- W2040332425 hasRelatedWork W2499394455 @default.
- W2040332425 hasRelatedWork W2738071409 @default.
- W2040332425 hasRelatedWork W2946559607 @default.
- W2040332425 hasRelatedWork W2953149112 @default.
- W2040332425 hasRelatedWork W3003467064 @default.
- W2040332425 hasVolume "210" @default.
- W2040332425 isParatext "false" @default.
- W2040332425 isRetracted "false" @default.
- W2040332425 magId "2040332425" @default.
- W2040332425 workType "article" @default.