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- W2040336582 abstract "The longitudinal 13C spin−lattice relaxation times and {1H}−13C nuclear Overhauser factors of the aliphatic and aromatic carbon atoms of calix[4]arene-p-sulfonic acid (1a) and its pentasodium salt (1b) were measured for a solution in D2O and a temperature range from 270 to 347 K; those of the calixarene (1a) were measured also for a solution in [2H4]methanol and from 203 to 324 K. The results show that the extreme narrowing condition is not fulfilled for the 13C relaxation data. For the aqueous solutions the longitudinal 2H spin−lattice relaxation times of D2O were determined as well. The observed relaxation times were fitted to the theoretical expressions for rotational motions of the molecules. The reorientational molecular dynamics showed Arrhenius behavior in all cases, and the corresponding activation parameters were evaluated. The rotational motion of the calixarene molecules is essentially isotropic in the investigated solutions. The order of the reorientation rates is methanolic solution of 1a > aqueous solution of 1b > aqueous solution of 1a. The differences in the motional behavior are an indication of differing intermolecular interaction mechanisms between solvent and solutes and, in the case of the aqueous solutions, a different dynamical behavior of the water around the calixarene molecules. A scaling of the spectral densities with the generalized order parameter S2 of the model-free approach by Lipari and Szabo has to be applied for quantitative interpretation of the relaxation data. This is caused by the existence of a very fast initial decay of the reorientational correlation function of the calixarene molecules, stemming from fast librational and/or internal motions in addition to the overall rotational diffusion process." @default.
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- W2040336582 date "1997-06-01" @default.
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- W2040336582 title "Structure and Dynamics of <i>p</i>-Sulfonatocalix[4]arene and Its Hydration Shell. Nuclear Magnetic Relaxation Results" @default.
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- W2040336582 doi "https://doi.org/10.1021/jp970691u" @default.
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