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- W2040346596 abstract "The spin-crossover phenomena of iron complexes accompany with molecular deformations such as symmetric breathing and trigonal torsion. Thus they can serve as a sensitive probe to molecular surroundings. A confinement effect into interlayer spaces of a clay host compound, NaTSM (sodium fluorotetrasilicic mica), was studied for iron complexes by magnetic susceptibility and 57 Fe Mössbauer spectroscopy. Guest complexes examined are [Fe II -(amp) 3 ] 2+ (amp=2-aminomethylpyridine), [Fe III (acpa) 2 ] + (Hacpa= N -(1-acetyl-2-propylidene)-2-pyridylmethylamine), and [Fe III - (sal 2 trien)] + (H 2 sal 2 trien= N , N ′-disalicylidenetriethylenetetramine). A remarkable reduction of the high spin-low spin energy gap in the interlayer space was observed." @default.
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- W2040346596 date "2002-01-01" @default.
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- W2040346596 title "Spin-crossover Phenomena of Iron Complexes in the NaTSM Intercalation Compounds" @default.
- W2040346596 doi "https://doi.org/10.1080/10587250210775" @default.
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