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- W2040349178 abstract "We have redetermined the molecular structure of trimethylsilylisocyanate in the gas phase by electron diffraction. An ra structure is defined with bond distances (pm) SiN 174.0(4). SiC 186.4(2), NC 120.2(16), CO 117.6(10) and CH 109.9(5), bond angles (degrees) HCSi 109.0(9), CSiC 108.8(25), SiNC 156.9(30) and NCO 165.8(36), with the NC bond eclipsing one SiC bond and the Me3Si group tilted slightly. The methyl groups are twisted 26.9(35)a from the position giving the Me3Si group C3v symmetry in an (assumed) concerted fashion. The apparent deviations from linearity of the SiN CO skeleton are shown to be compatible with a pseudolinear structure similar to that of SiH3NCO." @default.
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- W2040349178 date "1985-03-01" @default.
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- W2040349178 title "The molecular structure of trimethylsilylisocyanate in the gas phase redetermined by electron diffraction" @default.
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- W2040349178 doi "https://doi.org/10.1016/0022-2860(85)80015-6" @default.
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