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- W2040352567 abstract "We report preliminary results on the emission of fluorine atom from the (1 1 1) surface of CaF2 as a result of decay of free and self-trapped excitons. The main results are: (1) The self-trapped exciton (STE: F2− plus the excited electron) decays spontaneously on and near the surface and leads to the creation of an F center and an emission of a neutral F atom with a trajectory approaching the normal to the plane of surface. (2) The free (Frenkel-type) exciton on the surface decays and results in the fluorine atom desorption. The relaxation energy that can be imparted to the emitted atom is estimated. The difference between the alkali halides of NaCl structure and fluorites is discussed regarding the halogen desorption as well as the low temperature Frenkel pair creaton." @default.
- W2040352567 created "2016-06-24" @default.
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- W2040352567 date "1995-06-01" @default.
- W2040352567 modified "2023-10-14" @default.
- W2040352567 title "Excitonic instability and desorption of F atom from CaF2 crystal" @default.
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- W2040352567 doi "https://doi.org/10.1016/0168-583x(95)00066-6" @default.
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