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• W2040365290 abstract "Three-bond carbon-fluorine coupling constants of 32 substituted 3-fluoropropanes and 3-fluoropropanoates were measured. From these values and from those of other alicyclic compounds already known in the literature, it can be established that the influence of molecular parameters on 3J(FC) depends on the nature of the coupled carbon. When this carbon belongs to an alkyl group, the main molecular parameter is the dihedral angle [J(FC)g = 1.2 Hz and J(FC)t = 11.2 Hz]. When the carbon belongs to a carbethoxy group, more complex effects are observed: for one series the main parameter is the dihedral angle [J(FC)g = 0 Hz and J(FC)t = 20 Hz], and for other series the electronegativity and orientation of substituents particularly influence J(FC)g. Conversely, the diastereoisomers can be unambiguously identified from the 3J(HH), 3J(FH) and 3J(FC) values of both diastereoisomers." @default.
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• W2040365290 date "1986-04-01" @default.
• W2040365290 modified "2023-09-27" @default.
• W2040365290 title "Three-bond carbon-fluorine coupling constants in substituted 3-fluoropropanes and 3-fluoropropanoates" @default.
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• W2040365290 doi "https://doi.org/10.1002/mrc.1260240413" @default.
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